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Oct 24, 2022
Pt – Ag (– Cr) – ZnO – Pt

Summary

Process maturity: Stable

D1 having small size cell (SA5) exhibits stable switching. However, the instability exhibited in larger cell (SA60) can be avoided by introducing Cr barrier layer (D2). 

Active layer fabrication Data

Fabrication method:

Magnetron sputtering

Tool(s) used:

Angstrom

Main fabrication params:

Ar:O₂ (2/1) ratio and flows (30 sccm); temperature (assumed RT if not specified); power (30 W); pressure (10 mTorr).

 

Recipe

Ar:O

Temp

Comments

ZnO_7_10mT_50

20:10

25°C

Thickness 60 nm.

 

Electrode configuration

Top

Bottom

Tool

Comments

Pt/Ag

(10/30 nm)

Pt/Ti (25/50 nm)

LAB

Standard recipe. High pristine resistance (D1)

Pt/Ag/Cr

(10/30/7 nm)

Pt/Ti (25/50 nm)

LAB

Standard recipe. High pristine resistance (D2)

 

Indicative data

 

 

 

 

D1

Measurement: Formed devices (Vform ~1.3V); I-V characteristic; Reset voltage -2V; Complianceless;

Device stack: Pt/Ag/ZnO/Pt 10/30/60/25 (in nm, top to bottom); SA5.

Active layer recipe: ZnO_7_10mT_50

Comment: Device yield ~70%, stable DC endurance (ratio >102).

 

D1

Measurement: Formed devices (Vfrom ~1.3); I-V characteristic; Reset voltage -1.5V; Compliance 100μA .

Device stack: Pt/Ag/ZnO/Pt 10/30/60/25 (in nm, top to bottom); SA5.

Active layer recipe: ZnO_7_10mT_50

Comment: Device yield ~70%, stable DC endurance (ratio >10).

 

D2

Measurement: Formed devices (Vfrom ~2V); I-V characteristic; Reset voltage -1.5V; Compliance 1 mA.

Device stack: Pt/Ag/Cr/ZnO/Pt 10/30/7/60/25 (in nm, top to bottom); SA60.

Active layer recipe: ZnO_7_10mT_50

Comment: Device yield ~70%, stable DC endurance (ratio >10).